Product ID:AN SPRAY MARK OVER (C H FREE) TAN
MSDS Date:10/28/1991
FSC:7510
NIIN:00N030194
MSDS Number: BPDTN

MARSH CO

707 EAST B STREET
BELLEVILLE, IL 62222
US

Emergency Phone: 618-234-1122

Info Phone: 618-234-1122

Preparer: ENGINEERING/SAFETY DEPTS

Cage: GO822

MARSH COMPANY

388 BELLEVILLE, IL 62222 US

Telephone: 618-234-1122

Cage: 0MBZ9

4000 MG/KG

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: 1-5%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM; 9293

5000 MG/KG

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 1-5%

OSHA PEL 100 PPM; 150 STEL

ACGIH TLV: 100 PPM; 150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

9750 MG/KG

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 15-40%

OSHA PEL 1000PPM

ACGIH TLV: 750PPM/1000STEL;9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

HYDROCARBON PROPELLANT; (PROPANE/ISOBUTANE)

CAS: 68476-86-8

Fraction By Weight: 15-40%

ACGIH TLV: 900 PPM (MFR)

LIGROINE; (NAPHTHA)

CAS: 8032-32-4

RTECS: OI6180000

Fraction By Weight: 5-10%

OSHA PEL 300 PPM; 400 STEL

ACGIH TLV: 300 PPM

6900 MG/KG

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 5-10%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:VAPOR EXPOSURE MAY CAUSE HEADACHE,
DIZZINESS, NAUSEA, CARDIAC ARRYTHMIAS, CNS EFFECT, LIVER & KIDNEY
EFFECTS OR UNCONSCIOUSNESS. VAPOR MAY IRRITATE EYES. LIQUID MAY
CAUSE PAIN, MODEARATE EYE IRRITATIO N & TRANSIENT CORNEAL INJURY.
PROLONGEDSKIN CONTACT CAN CAUSE IRRITATION, DEFATTING OF SKIN &
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:POSSIBLY DERMATITIS. INGESTION CAN
CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING & DIARRHEA.
NOTE: TOLUENE CAS#108-88-3 APPEARS ON THE NAVY LISTING OF OCCUP
REPRO HAZARDS. SEEK CONSULTA TION FROM APPROP HEALTH PROFESSIONALS
CONCERNING LATEST HAZARD INFO AND SAFE HANDLING AND EXPOS
RECOMMENDATIONS .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:FLUSH W/WATER FOR AT LEAST 15 MINS & SEEK MEDICAL
ATTENTION. SKIN:REMOVE CONTAMINATED CLOTHING. WASH SKIN W/SOAP &
WATER. INHAL:REMOVE TO FRESH AIR, IF DISCOMFORT PERSISTS, SEEK
MEDICAL ATTENTION . INGEST:DO NOT INDUCE VOMITING. CALL MD
IMMEDIATELY.

Flash Point:-156F,-104C
Lower Limits:1.2
Upper Limits:9.5
Extinguishing Media:WATER FOG, CARBON DIOXIDE, DRY CHEMICAL & FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:EXPOSURE TO HEAT/TEMPERATURES ABOVE 120F
MAY CAUSE CANS TO EXPLODE RELEASING HIGHLY FLAMMABLE PROPELLANT.

Spill Release Procedures:ISOLATE FROM SOURCES OF IGNITION. VENTILATE TO
REMOVE PROPELLANT VAPORS. CONTAIN SPILL USING SUITABLE ABSORBENT.
CONTAINERIZE IN AN APPROVED DOT CONTAINER FOR PROPER DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:EXPOSURE TO TEMPEATURE ABOVE 120F MAY
CAUSE CONTAINER TO BURST, RELEASING THE HIGHLY FLAMMABLE
PROPELLANT.
Other Precautions:PROPELLANT VAPORS ARE HEAVIER THAN AIR. VENTILATE TO
PREVENT CONCENTRATION FROM REACHING FLAMMABLE LEVELS.

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR WHEN AIRBORNE
LEVELS MAY EXCEED PEL.
Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:AS NECESSARY TO AVOID PROLONGED CONTACT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
SPEC GRAV:0.82-0.92 (WATER=1)

HCC:V3
Boiling Pt:B.P. Text:-43F,-42C
Vapor Pres:60
Vapor Density:HEAVIER
Spec Gravity:SUPP DATA
Evaporation Rate & Reference:FASTER (N-BU AC=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:TAN OR WHITE W/SWEET SOLVENT ODOR.
Percent Volatiles by Volume:82

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:TEMPERATURES ABOVE 120F, SOURCES OF HEAT
OR IGNITION.
Hazardous Decomposition Products:CO.
Conditions to Avoid Polymerization:AVOID EXPOSURE TO HEAT & FLAME.

Waste Disposal Methods:DIPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.